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I think the buds secrete some kind of nectar that the ants are drinking. Everything that I've ever heard, however, says that the ants do no harm to the peonies while they're crawling on them.
The great thing about gardening is that you always get a chance to start over!
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Contraty to popular belief, the ants do not help open the buds, but they do like the secretions that the buds produce.